Synthesis and structural characterization of anion complexes with azacalix[2]dipyrrolylmethane: effect of anion charge on the conformation of the macrocycle-Reference-Cited by-同舟云学术

Synthesis and structural characterization of anion complexes with azacalix[2]dipyrrolylmethane: effect of anion charge on the conformation of the macrocycle

Published:2016 Issue:29 Volume:45 Page:11781-11790
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Guchhait Tapas¹²³⁴,Mani Ganesan¹²³⁴,Schulzke Carola⁵⁶⁷⁸

Affiliation:

1. Department of Chemistry

2. Indian Institute of Technology Kharagpur

3. Kharagpur

4. 721 302 India

5. Institut für Biochemie

6. Ernst-Moritz-Arndt Universität Greifswald

7. D-17487 Greifswald

8. Germany

Abstract

Azacalix[2]dipyrrolylmethane is flexible changing its 1,3-alternate conformation to the 1,2-alternate, partial cone or cone conformations with respect to the charge on the anion, as shown by a series of single crystal X-ray structures of inorganic mono- and dianionic complexes.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/DT/C6DT01396A

Reference61 articles.

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