Addition of phenylacetylene to a magnesium complex of monoiminoacenaphtheneone (dpp-mian)-Reference-Cited by-同舟云学术

Addition of phenylacetylene to a magnesium complex of monoiminoacenaphtheneone (dpp-mian)

Published:2015 Issue:47 Volume:44 Page:20532-20541
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Razborov D. A.¹²³⁴,Lukoyanov A. N.¹²³⁴,Baranov E. V.¹²³⁴,Fedushkin I. L.¹²³⁴

Affiliation:

1. G. A. Razuvaev Institute of Organometallic Chemistry

2. Russian Academy of Sciences

3. Nizhny Novgorod

4. Russian Federation

Abstract

Reaction of alkoxy-amido magnesium complex 4 with phenylacetylene affords cycloaddition product 6. The protonation of the latter with phenylacetylene results alkoxy-imino derivative 7.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/DT/C5DT03174E

Reference30 articles.

1. 1,3-Dipolar Cycloaddition to the Fe−OC Fragment. 19. Synthesis and Properties of Fe(CO)2(PR3)(R1NC(R2)−C(R3)O) and Fe(CO)(Ph2PCH2CH2PPh2)(R1NC(R2)−C(R3)O) and Their Reactivity toward Dipolarophiles. First X-ray Crystal Structure of the Initial Bicyclo[2.2.1] Adduct

2. Reaction of Ketones with 1,4-Diaza-1,3-diene Zirconium and Hafnium Complexes: First Example of a 1,3-Dipolar Cycloaddition Reaction of 1,4-Diaza-1,3-diene Complexes of Early Transition Metals

3. Reaction of Samarium 1,4-Diaza-1,3-diene Complexes with Ketones: Generation of a New Versatile Tridentate Ligand via 1,3-Dipolar Cycloaddition

4. Efficient triple coupling reaction to produce a self-adjusting molecular cage

5. Synthesis and structural characterisation of group 10 metal(ii) gallyl complexes: analogies with platinum diboration catalysts?

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