Tubular polyoxoanion [(SeMo6O21)2(C2O4)3]10− and its transformations
Author:
Affiliation:
1. Nikolaev Institute of Inorganic Chemistry SB RAS
2. Novosibirsk
3. Russia
4. Novosibirsk State University
5. South Ural State University
6. Chelyabinsk
Abstract
Tubular [(SeMo6O21)2(C2O4)3]10− polyoxoanion can be assembled from Na2MoO4/SeO2/H2C2O4 system. TBABr precipitates complexes of [Mo6O19]2− and [β-Mo8O26Na2(NO3)]3− from its aqueous solution. Speciation of [β-Mo8O26]4− and [Mo6O19]2− has been studied.
Publisher
Royal Society of Chemistry (RSC)
Subject
Materials Chemistry,General Chemistry,Catalysis
Link
http://pubs.rsc.org/en/content/articlepdf/2021/NJ/D1NJ00421B
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