The syntheses, structures and spectroelectrochemical properties of 6-oxo-verdazyl derivatives bearing surface anchoring groups-Reference-Cited by-同舟云学术

The syntheses, structures and spectroelectrochemical properties of 6-oxo-verdazyl derivatives bearing surface anchoring groups

Published:2022 Issue:5 Volume:10 Page:1896-1915
ISSN:2050-7526
Container-title:Journal of Materials Chemistry C
language:en
Short-container-title:J. Mater. Chem. C

Author:

Kumar Varshini J.¹^ORCID,Wu Jian-Zhong²^ORCID,Judd Martyna³,Rousset Elodie¹^ORCID,Korb Marcus¹^ORCID,Moggach Stephen A.¹^ORCID,Cox Nicholas³^ORCID,Low Paul J.¹^ORCID

Affiliation:

1. School of Molecular Sciences, University of Western Australia, 35 Stirling Highway, Crawley, Western Australia, 6009, Australia

2. School of Chemistry, South China Normal University, Guangzhou 510006, China

3. Research School of Chemistry, Australian National University, Canberra, ACT, 2601, Australia

Abstract

The electronic properties of 6-oxo-verdazyl radicals are tuned by substituents at the 1- and 5-positions, with frontier orbital analysis indicating that each system should display constructive quantum interference in a molecular junction.

Funder

Australian Research Council

Schlumberger Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/TC/D1TC05495C

Reference88 articles.

1. Verdazyls. Part 33. EPR and ENDOR studies of 6-oxo- and 6-thioxoverdazyls. X-Ray molecular structure of 1,3,5-triphenyl-6-oxoverdazyl and 3-tert-butyl-1,5-diphenyl-6-thioxoverdazyl

2. R. G.Hicks , Stable Radicals: Fundamentals and Applied Aspects of Odd-Electron Compounds , Wiley , Chippenham, Wiltshire, United Kingdom , 2010