Positive zero-field splitting and unexpected slow magnetic relaxation in the magneto-chemical calibrant HgCo(NCS)4
Author:
Affiliation:
1. Department of Chemistry
2. Faculty of Natural Sciences
3. University of Ss Cyril and Methodius
4. 917 01 Trnava
5. Slovakia
6. National High Magnetic Field Laboratory
7. Florida State University
8. Tallahassee
9. USA
Abstract
Magnetochemical standard HgCo(NCS)4 with positive zero-field splitting parameter D displays a slow magnetic relaxation strongly dependent upon the external magnetic field.
Funder
Agentúra na Podporu Výskumu a Vývoja
National Science Foundation
Vedecká Grantová Agentúra MŠVVaŠ SR a SAV
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2021/DT/D1DT00407G
Reference26 articles.
1. 61. Magnetochemistry. Part II. The temperature-dependence of the magnetic susceptibility of bivalent cobalt compounds
2. Magnetic Studies of High-spin Cobaltous Compounds. VII. Some Thiocyanate Complexes
3. Temperature dependence of the magnetic susceptibility of mercury tetrathiocyanatocobalt
4. Comment of the use of HgCo(NCS)4 as susceptibility standard
5. Standards for magnetic measurements. A comparison and a proposal for the use of tetramethylethylenediammonium tetrachlorocuprate(II)
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1. Magnetic anisotropies and slow magnetic relaxation of three tetrahedral tetrakis(pseudohalido)–cobalt(ii) complexes;New Journal of Chemistry;2021
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