Vitamin B1-based thiazol-2-ylidene–Ru(<scp>ii</scp>) complexes: recyclable transfer hydrogenation catalysts in water-Reference-Cited by-同舟云学术

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Vitamin B1-based thiazol-2-ylidene–Ru(ii) complexes: recyclable transfer hydrogenation catalysts in water

Published:2024 Issue:21 Volume:53 Page:9192-9197
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Kılınçarslan Rafet¹^ORCID,Tuncer Hayriye¹,Özdemir Namık²^ORCID,Çetinkaya Bekir³

Affiliation:

1. Pamukkale University, Faculty of Science, Department of Chemistry, 20070, Denizli, Turkey

2. Ondokuz Mayıs University, Faculty of Science, Department of Physics, 55139, Samsun, Turkey

3. Ege University, Faculty of Science, Department of Chemistry, 35100, İzmir, Turkey

Abstract

In order to develop recyclable catalyst in water, vitamin B1 based Ru(ii)-NHC complexes (2–4) were synthesized and evaluated for transfer hydrogenation of ketones and aldehydes with an azeotropic mixture of HCOOH/Et3N in water. The complex,4 exhibited excellent catalytic activity and recyclability.

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/DT/D4DT00445K

Reference59 articles.

1. Asymmetric Transfer Hydrogenation of Aromatic Ketones Catalyzed by Chiral Ruthenium(II) Complexes

2. Ruthenium(II)-Catalyzed Asymmetric Transfer Hydrogenation of Ketones Using a Formic Acid−Triethylamine Mixture

3. New C2-symmetrical ferrocenyl diamines as ligands for ruthenium catalyzed transfer hydrogenation

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