Polyacrylonitrile-containing amphiphilic block copolymers: self-assembly and porous membrane formation

Author:

Gemmer Lea1,Niebuur Bart-Jan2ORCID,Dietz Christian3ORCID,Rauber Daniel4ORCID,Plank Martina5,Frieß Florian V.1,Presser Volker467ORCID,Stark Robert W.3ORCID,Kraus Tobias28ORCID,Gallei Markus17ORCID

Affiliation:

1. Polymer Chemistry, Universität des Saarlandes, Campus C4 2, 66123 Saarbrücken, Germany

2. INM – Leibniz-Institute for New Materials, Campus D2 2, 66123 Saarbrücken, Germany

3. Physics of Surfaces, Institute of Materials Science, Technische Universität Darmstadt, Peter-Grünberg-Straße 2, 64287 Darmstadt, Germany

4. Department of Materials Science and Engineering, Saarland University, 66123 Saarbrücken, Germany

5. Ernst-Berl Institute of Technical and Macromolecular Chemistry, Technische Universität Darmstadt, Peter-Grünberg-Straße 4, 64287 Darmstadt, Germany

6. INM - Leibniz-Institute for New Materials, Campus D2 2, 66123 Saarbrücken, Germany

7. Saarene, Saarland Center for Energy Materials and Sustainability, Campus C4 2, 66123 Saarbrücken, Germany

8. Colloid and Interface Chemistry, Universität des Saarlandes, Campus D2 2, 66123 Saarbrücken, Germany

Abstract

Porous nanostructures were derived after self-assembly of amphiphilic poly(acrylonitrile)-containing block copolymers. The introduction of acrylonitrile moieties within the membrane matrix was shown to improve the membranes’ mechanical properties.

Funder

Saarland University

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Polymers and Plastics,Biochemistry,Bioengineering

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