How does chiral self-sorting take place in the formation of homochiral Pd6L8 capsules consisting of cyclotriveratrylene-based chiral tritopic ligands?-Reference-Cited by-同舟云学术

How does chiral self-sorting take place in the formation of homochiral Pd6L8 capsules consisting of cyclotriveratrylene-based chiral tritopic ligands?

Published:2018 Issue:17 Volume:9 Page:4104-4108
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Kai Shumpei¹²³⁴⁵,Kojima Tatsuo¹²³⁴⁵^ORCID,Thorp-Greenwood Flora L.⁶⁷⁸⁹,Hardie Michaele J.⁶⁷⁸⁹^ORCID,Hiraoka Shuichi¹²³⁴⁵^ORCID

Affiliation:

1. Department of Basic Science

2. Graduate School of Arts and Sciences

3. The University of Tokyo

4. Tokyo 153-8902

5. Japan

6. School of Chemistry

7. University of Leeds

8. Leeds LS2 9JT

9. UK

Abstract

The chiral self-sorting in the formation of homochiral Pd₆L₈ capsules consisting of cyclotriveratrylene (CTV)-based chiral tritopic ligands and Pd(ii) ions takes place through the initial formation of heterochiral Pd₆L₈X₂ (X indicates a leaving ligand) immature capsules (ICs) followed by the correction of chirality in the ICs assisted by the free tritopic ligands to lead to the homochiral capsules.

Funder

Japan Society for the Promotion of Science

Asahi Glass Foundation

Leverhulme Trust

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2018/SC/C8SC01062E

Reference20 articles.

1. Making a Right or Left Choice: Chiral Self-Sorting as a Tool for the Formation of Discrete Complex Structures