Controlled oligomeric guest stacking by cucurbiturils in water

Author:

Liu Fengbo1ORCID,Kriat Amine2,Rosas Roselyne3,Bergé-Lefranc David2,Gigmes Didier2ORCID,Pascal Simon4ORCID,Siri Olivier4ORCID,Liu Simin1ORCID,Kermagoret Anthony4ORCID,Bardelang David2ORCID

Affiliation:

1. School of Chemistry and Chemical Engineering, Wuhan University of Science and Technology, Wuhan 430081, People's Republic of China

2. Aix Marseille Univ, CNRS, ICR, AMUTech, Marseille, France

3. Aix Marseille Univ, CNRS, FSCM, Spectropole, Marseille, France

4. Aix Marseille Univ, CNRS, CINAM, AMUTech, Marseille, France

Abstract

The macrocycles cucurbit[n]urils (CB[n], n = 8, 10) are shown to control the stacking in solution of linear, donor–acceptor molecules, with almost quantitative conversions toward supramolecular guest dimers or trimers.

Funder

Fondation Aix-Marseille Universite

Aix-Marseille Université

Centre National de la Recherche Scientifique

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

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