Reversible C–H bond silylation with a neutral silicon Lewis acid-Reference-Cited by-同舟云学术

Reversible C–H bond silylation with a neutral silicon Lewis acid

Published:2023 Issue:40 Volume:14 Page:11237-11242
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Thorwart Thaddäus¹,Greb Lutz¹^ORCID

Affiliation:

1. Ruprecht-Karls-Universität Heidelberg, Anorganisch-Chemisches Institut, Im Neuenheimer Feld 270, Heidelberg 69120, Germany

Abstract

A perfluorinated bis(ortho-amidophenolato)silane combined with a bulky Lewis base enables the first neutral silicon Lewis acid mediated C–H bond silylation. It can be reversed upon adding a donor and modulates the follow-up chemistry with electrophiles.

Funder

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/SC/D3SC03488G

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5. Scalable Synthesis of Interconnected Porous Silicon/Carbon Composites by the Rochow Reaction as High‐Performance Anodes of Lithium Ion Batteries

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