[Ge9{M(CO)5}3]4−: electrophilic addition of M(CO)5and [E9]4−Zintl anions (M = Cr, Mo, W)-Reference-Cited by-同舟云学术

[Ge9{M(CO)5}3]4−: electrophilic addition of M(CO)5and [E9]4−Zintl anions (M = Cr, Mo, W)

Published:2017 Issue:21 Volume:46 Page:6839-6842
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Wang Lulu¹²³⁴⁵,Wang Yi¹²³⁴,Li Zhenyu¹²³⁴⁵,Ruan Huapeng¹²³⁴⁵,Xu Li¹²³⁴^ORCID

Affiliation:

1. Department State Key Laboratory of Structural Chemistry

2. Institution Fujian Institute of Research on the Structure of Matter Chinese Academy of Sciences

3. Fuzhou

4. P. R. China

5. University of the Chinese Academy of Science

Abstract

Electrophilic addition of M(CO)₅and [E₉]ⁿ⁻at the three capping sites was achieved by the nucleophilic substitution reactions of K₄Ge₉and M(CO)₆, which produced the novelC_3h-[Ge₉{M(CO)₅}₃]⁴⁻(M = Cr,1; Mo,2; W,3) exhibiting a perfect tricapped trigonal prismatic core structure.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/DT/C7DT01123G

Reference36 articles.

1. Chemistry of Deltahedral Zintl Ions

2. Zintl Ions, Cage Compounds, and Intermetalloid Clusters of Group 14 and Group 15 Elements

3. Oxidative Coupling of Deltahedral [Ge9]4- Zintl Ions

4. [Ge8(Mo(CO)3)2]4−: an unprecedented 20-electron empty ten-vertex Zintl cluster

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