Solvent-free heterogeneous catalysis for cyanosilylation in a dynamic cobalt-MOF

Author:

Cui Xin1234,Xu Mei-Chen1234,Zhang Ling-Juan1234,Yao Ru-Xin1234,Zhang Xian-Ming1234

Affiliation:

1. Department of Chemistry & Material Science

2. Shanxi Normal University

3. Linfen 041004

4. P. R. China

Abstract

The terminal coordinated water molecule has been successfully removed in a butterfly-like cobalt cluster based 3D frameworks by SCSC transformation, which can efficiently heterogeneous catalyze cyanosilylation of aldehydes and exhibit size-selectivity effect under solvent-free conditions.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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