Inorganic–organic hybrid polyoxovanadates based on [V4O12]4− or [VO3]22− clusters: controllable synthesis, crystal structures and catalytic properties in selective oxidation of sulfides-Reference-Cited by-同舟云学术

Inorganic–organic hybrid polyoxovanadates based on [V4O12]4− or [VO3]22− clusters: controllable synthesis, crystal structures and catalytic properties in selective oxidation of sulfides

Published:2020 Issue:40 Volume:49 Page:14148-14157
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Li Jikun¹²³⁴⁵,Wei Chuanping¹²³⁴,Guo Daigaojie¹²³⁴,Wang Congcong¹²³⁴,Han Yinfeng¹²³⁴,He Guofang¹²³⁴,Zhang Jianping¹²³⁴,Huang Xianqiang⁶⁷⁸⁹⁴^ORCID,Hu Changwen⁵¹⁰¹¹¹²¹³^ORCID

Affiliation:

1. College of Chemistry and Chemical Engineering

2. Taishan University

3. Tai'an

4. P. R. China

5. Key Laboratory of Cluster Science Ministry of Education

6. Shandong Provincial Key Laboratory of Chemical Energy Storage and Novel Cell Technology

7. School of Chemistry & Chemical Engineering

8. Liaocheng University

9. Liaocheng

10. Beijing Key Laboratory of Photoelectronic/Electrophotonic

11. School of Chemistry

12. Beijing Institute of Technology

13. Beijing

Abstract

Three inorganic–organic hybrid polyoxovanadates have been synthesized. Among them, complex [Ni₂(1-vIM)₇H₂O][V₄O₁₂]·H₂O (1) exhibits extraordinary heterogeneous catalytic performance in the selective oxidation of sulfides using H₂O₂ as the oxidant.

Funder

National Natural Science Foundation of China

Natural Science Foundation of Shandong Province

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/DT/D0DT03015E

Reference55 articles.

1. Epoxidation of olefins with hydrogen peroxide catalyzed by polyoxometalates

2. Polyoxometalate clusters, nanostructures and materials: From self assembly to designer materials and devices