Two-step solid-state synthesis of PEPPSI-type compounds

Author:

Adams Christopher J.1234,Lusi Matteo1234ORCID,Mutambi Emily M.1234,Guy Orpen A.1234

Affiliation:

1. School of Chemistry

2. University of Bristol

3. Bristol

4. UK

Abstract

The two-step mechanochemical preparation of an important class of organometallic compounds is reported. The carbene–metal complexes are all rapidly formed in excellent yield. The solvent-free synthesis is proved to be a viable synthetic route to useful NHC-containing compounds amenable to scale-up and mechanization.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Reference21 articles.

1. Mechanochemistry: opportunities for new and cleaner synthesis

2. See CrystEngComm, Mechanochemistry and cocrystals, 2009, issue 3, pages 375 to 522; CrystEngComm Dynamic behaviour and reactivity in crystalline solids, 2011, issue 13, pages 4291 to 4438; ChemComm Mechanochemistry: fundamentals and applications in synthesis web themed issue, http://pubs.rsc.org/en/journals/articlecollectionlanding?sercode=cc&themeid=6608cfd9-e113-499d-8069-3691fd2efb77&journalname=chemical%20communications&e=1

3. Stereospecific Addition of Hydrogen Halides to Tetragonal d8 Complexes

4. Organometallic chemistry in the solid state

5. Easily Prepared Air- and Moisture-Stable Pd–NHC (NHC=N-Heterocyclic Carbene) Complexes: A Reliable, User-Friendly, Highly Active Palladium Precatalyst for the Suzuki–Miyaura Reaction

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