A pseudo-icosahedral cage {Gd12} based on aminomethylphosphonate-Reference-Cited by-同舟云学术

A pseudo-icosahedral cage {Gd12} based on aminomethylphosphonate

Published:2016 Issue:22 Volume:45 Page:9041-9044
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Zhang Ze-Min¹²³⁴⁵,Zangana Karzan H.⁶⁷⁸⁹¹⁰,Kostopoulos Andreas K.⁶⁷⁸⁹,Tong Ming-Liang¹²³⁴⁵,Winpenny Richard E. P.⁶⁷⁸⁹

Affiliation:

1. Key Laboratory of Bioinorganic and Synthetic Chemistry of Ministry of Education

2. School of Chemistry & Chemical Engineering

3. Sun Yat-Sen University

4. Guangzhou

5. P. R. China

6. School of Chemistry

7. The University of Manchester

8. Manchester

9. UK

10. Departent of Chemistry

Abstract

Reaction of (aminomethyl)phosphonic acid (ampH₂) with a mixture of gadolinium and cobalt pivalates under solvothermal conditions, led to a pseudo-icosahedral cage {Gd₁₂}, which shows a large magnetocaloric effect (MCE).

Funder

Engineering and Physical Sciences Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/DT/C6DT00876C

Reference32 articles.

1. Metal Phosphonate Chemistry: From Synthesis to Applications, ed. A. Clearfield and K. Demadis, Royal Society of Chemistry, Cambridge, 2011, and references therein

2. 3d–4f Clusters with large spin ground states and SMM behaviour

3. The use of phosphonates for constructing 3d–4f clusters at high oxidation states: synthesis and characterization of two unusual heterometallic CeMn complexes

4. Large Magnetocaloric Effect in a Wells-Dawson Type {Ni6Gd6P6} Cage

5. Co–Ln Mixed-Metal Phosphonate Grids and Cages as Molecular Magnetic Refrigerants

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