NH bond activation of ammonia and amines by ditetrelenes: key insights into the stereochemistry of nucleophilic addition-Reference-Cited by-同舟云学术

NH bond activation of ammonia and amines by ditetrelenes: key insights into the stereochemistry of nucleophilic addition

Published:2021 Issue:47 Volume:50 Page:17734-17750
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

McOnie Sarah L.¹^ORCID,Özpınar Gül Altınbaş²^ORCID,Bourque Jeremy L.¹,Müller Thomas²^ORCID,Baines Kim M.¹^ORCID

Affiliation:

1. Department of Chemistry, University of Western Ontario, London, Ontario, Canada N6A 5B7

2. Institut für Chemie, Carl von Ossietzky Universität Oldenburg, D-26129 Oldenburg, Federal Republic of Germany, European Union

Abstract

The NH activation of ammonia by tetramesityldisilene takes place in three steps: formation of the anti-ammonia-disilene adduct, inversion at the β-silicon, and intramolecular syn-transfer of the proton to give the syn-product.

Funder

Deutsche Forschungsgemeinschaft

Niedersächsische Ministerium für Wissenschaft und Kultur

Western University

Natural Sciences and Engineering Research Council of Canada

Alexander von Humboldt-Stiftung

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/DT/D1DT03739K

Reference55 articles.

1. Ammonia Activation, H2 Evolution and Nitride Formation from a Molybdenum Complex with a Chemically and Redox Noninnocent Ligand

2. Ammonia Activation by a Nickel NCN-Pincer Complex featuring a Non-Innocent N-Heterocyclic Carbene: Ammine and Amido Complexes in Equilibrium

3. Rhodium and Iridium Amido Complexes Supported by Silyl Pincer Ligation: Ammonia N−H Bond Activation by a [PSiP]Ir Complex

4. Enabling and Probing Oxidative Addition and Reductive Elimination at a Group 14 Metal Center: Cleavage and Functionalization of E–H Bonds by a Bis(boryl)stannylene

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1. On the Stereochemistry of the NH Bond Activation of Ammonia or Amines by Disilenes: Predictability;Chemistry – A European Journal;2023-05-19

2. Facile reduction of phosphine oxides and H-phosphonates by ditetrelenes;Canadian Journal of Chemistry;2023-03-01