Mechanism and origin of the stereoselectivity of manganese-catalyzed hydrosilylation of alkynes: a DFT study-Reference-Cited by-同舟云学术

Mechanism and origin of the stereoselectivity of manganese-catalyzed hydrosilylation of alkynes: a DFT study

Published:2022 Issue:8 Volume:12 Page:2649-2658
ISSN:2044-4753
Container-title:Catalysis Science & Technology
language:en
Short-container-title:Catal. Sci. Technol.

Author:

Li Qianqian¹,Huo Suhong²,Meng Lingpeng¹^ORCID,Li Xiaoyan¹^ORCID

Affiliation:

1. Hebei Key Laboratory of Inorganic and Nano-Materials, College of Chemistry and Materials Science, Hebei Normal University, Road East of 2nd Ring South, Shijiazhuang, 050024, China

2. School of Safety Supervision, North China Institute of Science and Technology, No. 467 academy Street, Sanhe Yanjiao Development Zone, Langfang, 065201, China

Abstract

The mechanism and origin of the stereodivergent mononuclear Mn(CO)5Br and binuclear Mn2(CO)10 catalyzed hydrosilylation of alkynes have been investigated and compared.

Funder

National Natural Science Foundation of China

Natural Science Foundation of Hebei Province

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2022/CY/D1CY02340C

Reference51 articles.

1. Catalysis by transition metal complexes of alkene silylation–recent progress and mechanistic implications

2. A Review of Recent Progress in Catalyzed Homogeneous Hydrosilation (Hydrosilylation)