Solution structure of a pentachromium(ii) single molecule magnet from DFT calculations, isotopic labelling and multinuclear NMR spectroscopy-Reference-Cited by-同舟云学术

Solution structure of a pentachromium(ii) single molecule magnet from DFT calculations, isotopic labelling and multinuclear NMR spectroscopy

Published:2018 Issue:2 Volume:47 Page:585-595
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Dirvanauskas Aivaras¹²³⁴⁵,Galavotti Rita¹²³⁴,Lunghi Alessandro⁶⁷⁸⁴^ORCID,Nicolini Alessio¹²³⁴,Roncaglia Fabrizio¹²³⁴^ORCID,Totti Federico⁶⁷⁸⁴^ORCID,Cornia Andrea¹²³⁴^ORCID

Affiliation:

1. Department of Chemical and Geological Sciences

2. University of Modena and Reggio Emilia & INSTM

3. I-41125 Modena

4. Italy

5. Department of Chemistry

6. Department of Chemistry ‘Ugo Schiff’

7. University of Florence & INSTM

8. I-50019 Sesto Fiorentino (FI)

Abstract

Solution NMR spectroscopy on isotopically-labelled samples of [Cr₅(tpda)₄Cl₂] unveils a D₄ symmetric molecule, implying fast shuttling between the two unsymmetric ground configurations over NMR timescale.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2018/DT/C7DT03931J

Reference77 articles.

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2. Low-symmetry distortions in Extended Metal Atom Chains (EMACs): Origins and consequences for electron transport

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4. Attenuation of Conductance in Cobalt Extended Metal Atom Chains

5. Influence of Low-Symmetry Distortions on Electron Transport through Metal Atom Chains: When Is a Molecular Wire Really “Broken”?

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