Photophysical dynamics of the efficient emission and photosensitization of [Ir(pqi)2(NN)]+complexes

Author:

Zanoni Kassio P. S.12345ORCID,Ito Akitaka6789ORCID,Grüner Malte12345,Murakami Iha Neyde Y.101112313ORCID,de Camargo Andrea S. S.12345

Affiliation:

1. Laboratório de Espectroscopia de Materiais Funcionais

2. Instituto de Física de São Carlos

3. Universidade de São Paulo

4. São Carlos

5. Brazil

6. School of Environmental Science and Engineering and Research Center for Material Science and Engineering

7. Kochi University of Technology

8. Kochi 782-8502

9. Japan

10. Laboratório de Fotoquímica e Conversão de Energia

11. Departamento de Química Fundamental

12. Instituto de Química

13. São Paulo

Abstract

Rational photophysical investigation through experimental and theoretical analyses reveals the photophysical dynamics of the highly-emissive [Ir(pqi)2(NN)]+complex series, with remarkable emission quantum yields and efficient generation of singlet oxygen.

Funder

Japan Society for the Promotion of Science

Fundação de Amparo à Pesquisa do Estado de São Paulo

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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