Oxidoperoxidomolybdenum(vi) complexes with acylpyrazolonate ligands: synthesis, structure and catalytic properties-Reference-Cited by-同舟云学术

Oxidoperoxidomolybdenum(vi) complexes with acylpyrazolonate ligands: synthesis, structure and catalytic properties

Published:2018 Issue:1 Volume:47 Page:197-208
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Begines Emilio¹²³⁴⁵,Carrasco Carlos J.¹²³⁴⁵,Montilla Francisco¹²³⁴⁵^ORCID,Álvarez Eleuterio⁶⁷⁸⁵^ORCID,Marchetti Fabio⁹¹⁰¹¹¹²^ORCID,Pettinari Riccardo⁹¹⁰¹¹¹²^ORCID,Pettinari Claudio¹³¹⁰¹¹¹²^ORCID,Galindo Agustín¹²³⁴⁵^ORCID

Affiliation:

1. Departamento de Química Inorgánica

2. Facultad de Química

3. Universidad de Sevilla

4. 41071 Sevilla

5. Spain

6. Instituto de Investigaciones Químicas

7. CSIC-Universidad de Sevilla

8. 41092 Sevilla

9. School of Sciences and Technologies

10. University of Camerino

11. 62032 Camerino MC

12. Italy

13. School of Pharmacy

Abstract

Oxidoperoxido–molybdenum(vi) complexes Ph₄P[Mo(O)(O₂)₂(Q^R)] and [Mo(O)(O₂)(Q^R)₂] (Q^R = acylpyrazolonate ligands) were synthesised and tested as catalysts in epoxidation, sulphoxidation and epoxide deoxygenation.

Funder

Consejería de Economía, Innovación, Ciencia y Empleo, Junta de Andalucía

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2018/DT/C7DT03939E

Reference74 articles.

1. Recent advances in acylpyrazolone metal complexes and their potential applications

2. Acylpyrazolone ligands: Synthesis, structures, metal coordination chemistry and applications

3. Selective catalytic oxidation of olefins by novel oxovanadium(iv) complexes having different donor ligands covalently anchored on SBA-15: a comparative study