Understanding Cu(ii)-based systems for C(sp3)–H bond functionalization: insights into the synthesis of aza-heterocycles-Reference-Cited by-同舟云学术

Understanding Cu(ii)-based systems for C(sp3)–H bond functionalization: insights into the synthesis of aza-heterocycles

Published:2022 Issue:1 Volume:20 Page:219-227
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Camats Marc¹,Favier Isabelle¹,Mallet-Ladeira Sonia²,Pla Daniel¹^ORCID,Gómez Montserrat¹^ORCID

Affiliation:

1. Laboratoire Hétérochimie Fondamentale et Appliquée, CNRS UMR 5069, Université Toulouse 3 – Paul Sabatier, 118 route de Narbonne, 31062 Toulouse Cedex 09, France

2. Institut de Chimie de Toulouse, CNRS UAR 2599, 118 Route de Narbonne, Toulouse 31062 Cedex 09, France

Abstract

Carboxylate-assisted Cu(ii)-catalyzed relay towards the synthesis of imidazo[1,5-a]pyridines encompassing C(sp3)–H amination and cyclization of aldimines followed by C(sp2)–H cyanation, is reported.

Funder

Centre National de la Recherche Scientifique

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/OB/D1OB02118D

Reference115 articles.

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2. Palladium-catalysed C–H activation of aliphatic amines to give strained nitrogen heterocycles

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4. Synthesis of Stilbenes by Rhodium-Catalyzed Aerobic Alkenylation of Arenes via C–H Activation

5. Acetylene, ethylene, and arene chemistry of palladium surfaces

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