A computational investigation of orbital overlap versus energy degeneracy covalency in [UE2]2+ (E = O, S, Se, Te) complexes-Reference-Cited by-同舟云学术

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A computational investigation of orbital overlap versus energy degeneracy covalency in [UE2]2+ (E = O, S, Se, Te) complexes

Published:2020 Issue:4 Volume:49 Page:1077-1088
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Platts James A.¹²³⁴^ORCID,Baker Robert J.¹⁵⁶⁷⁸^ORCID

Affiliation:

1. School of Chemistry

2. Cardiff University

3. Cardiff CF10 3AT

4. UK

5. University of Dublin

6. Trinity College

7. Dublin 2

8. Ireland

Abstract

Covalency in analogues of uranyl with heavy chalcogens is explored using DFT, and traced to increased energy-degeneracy as the group is descended.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/DT/C9DT04484A

Reference69 articles.

1. F. A. Cotton , G.Wilkinson , C. A.Murillo and M.Bochmann , Advanced Inorganic Chemistry , Wiley , 6th edn, 1999

2. An Ion-exchange Study of Possible Hybridized 5f Bonding in the Actinides1

3. Two isostructural actinide .pi. complexes. Crystal and molecular structure of bis(cyclooctatetraenyl)uranium(IV), U(C8H8)2, and bis(cyclooctatetraenyl)thorium(IV), Th(C8H8)2

4. Bis(.eta.8-1,3,5,7-tetramethylcyclooctatetraene) compounds of protactinium, neptunium, and plutonium

5. Bis(cyclooctatetraenyl)uranium (uranocene). A new class of sandwich complexes that utilize atomic f orbitals

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3. Linearity and Chemical Bond of UO₂²⁺ Revisited: A Comparison Study with UN₂ and UE₂²⁺ (E = S, Se, and Te) Based on Relativistic Calculations;The Journal of Physical Chemistry A;2022-11-14

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