Changes in macrocyclic aromaticity and formation of a charge-separated state by complexation of expanded porphyrin and C60

Author:

Cha Won-Young12345,Ahn Ahreum6784,Kim Taeyeon1234,Oh Juwon1234,Ali Rashid1234,Park Jung Su1234,Kim Dongho1234ORCID

Affiliation:

1. Department of Chemistry and Spectroscopy Laboratory for Functional π-Electronic Systems

2. Yonsei University

3. Seoul 03722

4. Korea

5. Department of Molecular Engineering, Graduate School of Engineering

6. Center for Supercomputing Applications

7. Korea Institute of Science and Technology Information

8. Daejeon 34141

Abstract

Significant changes of macrocyclic aromaticity in expanded porphyrins through C60 complexation were studied by 1H NMR spectroscopy and nucleus-independent chemical shift calculations.

Funder

National Research Foundation of Korea

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

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