Syntheses and characterization of aryl-substituted pyrogallol[4]arenes and resorcin[4]arenes

Author:

Pfeiffer Constance R.123,Feaster Kyle A.123,Dalgarno Scott J.456,Atwood Jerry L.123

Affiliation:

1. Department of Chemistry

2. University of Missouri-Columbia

3. Columbia, USA

4. Institute of Chemical Sciences

5. Heriot-Watt University

6. Edinburgh, UK

Abstract

Thirteen aryl-substituted pyrogallol[4]arene and resorcin[4]arenes structures are synthesized and characterized. The effect of the varying aryl pendent groups on π–π distance, the inward tilt of the pendent –R groups, the twist angle of the pendent –R groups, and the angle between the pendent –R groups is methodically investigated and discussed.

Funder

Division of Chemistry

Publisher

Royal Society of Chemistry (RSC)

Subject

Condensed Matter Physics,General Materials Science,General Chemistry

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