Catalytic asymmetric synthesis of pyrrolidine derivatives bearing heteroatom-substituted quaternary stereocenters-Reference-Cited by-同舟云学术

Catalytic asymmetric synthesis of pyrrolidine derivatives bearing heteroatom-substituted quaternary stereocenters

Published:2018 Issue:1 Volume:5 Page:36-40
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Wang Zhi-Peng¹²³⁴⁵,Wu Qi¹²³⁴⁵,Jiang Jia¹²³⁴⁵,Li Zi-Rui¹²³⁴⁵,Peng Xiao-Jiao¹²³⁴⁵,Shao Pan-Lin¹²³⁴⁵^ORCID,He Yun¹²³⁴⁵^ORCID

Affiliation:

1. Chongqing Key Laboratory of Natural Product Synthesis and Drug Research

2. School of Pharmaceutical Sciences

3. Chongqing University

4. Chongqing 401331

5. P.R. China

Abstract

An enantioselective [3 + 2] cycloaddition of heteroatom-substituted alkenes with α-substituted isocyanoacetates has been developed. Excellent reactivity and enantioselectivity were obtained.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2018/QO/C7QO00692F

Reference67 articles.

1. Isocyanoacetate Derivatives: Synthesis, Reactivity, and Application

2. Isocyanides in the Synthesis of Nitrogen Heterocycles

3. An Unexpected Silver Triflate Catalyzed Reaction of 2-Alkynylbenzaldehyde with 2-Isocyanoacetate

4. New Insights into Aldol Reactions of Methyl Isocyanoacetate Catalyzed by Heterogenized Homogeneous Catalysts

5. Asymmetric [3 + 2] Cycloaddition of Chiral N-Phosphonyl Imines with Methyl Isocyanoacetate for Accessing 2-Imidazolines with Switchable Stereoselectivity

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