Unconventional poly(ionic liquid)s combining motionless main chain 1,2,3-triazolium cations and high ionic conductivity

Author:

Colliat-Dangus Guillaume12345,Obadia Mona M.12345,Vygodskii Yakov S.678,Serghei Anatoli12345,Shaplov Alexander S.678ORCID,Drockenmuller Eric12345

Affiliation:

1. Université de Lyon 1

2. Ingénierie des Matériaux Polymères (IMP

3. UMR CNRS 5223)

4. 69622 Villeurbanne Cedex

5. France

6. A.N. Nesmeyanov Institute of Organoelement Compounds Russian Academy of Sciences (INEOS RAS)

7. Moscow

8. Russia

Abstract

We report the synthesis of poly(1,2,3-triazolium ionic liquid)s by the polyaddition of α-azide-ω-alkyne monomers with short n-hexyl and diethylene glycol spacers by both copper(I)-catalyzed and thermal Huisgen azide–alkyne 1,3-dipolar cycloaddition.

Funder

Institut Universitaire de France

Russian Foundation for Basic Research

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Polymers and Plastics,Biochemistry,Bioengineering

Reference47 articles.

1. Recent Advances in Innovative Polymer Electrolytes based on Poly(ionic liquid)s

2. H. Ohno and M.Yoshizawa, in Ionic Liquids IIIB: Fundamentals, Progress, Challenges, and Opportunities: Transformations and Processes, American Chemical Society, Washington, DC, 2005, pp. 159–170

3. Polymeric ionic liquids: Broadening the properties and applications of polyelectrolytes

4. Poly(ionic liquid)s: An update

5. Recent trends in the synthesis of polyelectrolytes

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