Dimerization of ethene in a fluidized bed reactor using Ni-based Supported Ionic Liquid Phase (SILP) catalysts

Author:

Kohler Florian T. U.1234,Gärtner Konstantin1234,Hager Veit1234,Haumann Marco1234,Sternberg Michelle5634,Wang Xinjiao5634,Szesni Normen78,Meyer Karsten5634,Wasserscheid Peter1234

Affiliation:

1. Department of Chemical and Bioengineering

2. Chemical Reaction Engineering

3. University Erlangen-Nuremberg

4. D-91058 Erlangen, Germany

5. Department of Chemistry and Pharmacy

6. Inorganic Chemistry

7. Clariant Produkte (Deutschland) GmbH

8. D-83052 Bruckmühl, Germany

Abstract

Ethene dimerization to 2-butenes was catalyzed by Ni-SILP complexes for the first time in a fluidized bed to improve heat removal.

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

Reference55 articles.

1. Evolving Propylene Sources, Solution to Supply Shortages? , Chemsystems Prospectus, January 2012

2. H. Zimmermann and R.Walzl , Ethylene , in Ullmann's Encyclopedia of Industrial Chemistry , Wiley-VCH Verlag GmbH & Co. KGaA , 2000

3. P. Eisele and R.Killpack , Propene , in Ullmann's Encyclopedia of Industrial Chemistry , Wiley-VCH Verlag GmbH & Co. KGaA , 2000

4. Highly selective conversion of ethene to propene over SAPO-34 as a solid acid catalyst

5. Conversion of methane into higher hydrocarbons in the presence of ethylene over H-ZSM-5 loaded with silver cations

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