Efficient amine oxidation using metal–organic framework photocatalysts for aminoalkyl radical-mediated halogen-atom transfer

Author:

Liu Xin1,Guo Zhifen1,Che Yan1,Liu Xingbing1,Yu Min1,Lv Jiahuan1,Li Mengying1,Xing Hongzhu1ORCID,Chen Peng2

Affiliation:

1. Laboratory of Advanced Energy Materials, College of Chemistry, Northeast Normal University, Changchun 130021, China

2. Key Laboratory of Functional Inorganic Material Chemistry (MOE), School of Chemistry and Materials Science, Heilongjiang University, Harbin 150080, China

Abstract

Efficient photooxidation of amines by visible-light-responsive metal–organic frameworks generating α-aminoalkyl radicals to achieve halogen-atom transfer (XAT) reactions of dehalogenation, hydroalkylation and polyfluoroarylation.

Funder

Fundamental Research Funds for the Central Universities

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

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