Efficient amine oxidation using metal–organic framework photocatalysts for aminoalkyl radical-mediated halogen-atom transfer-Reference-Cited by-同舟云学术

Efficient amine oxidation using metal–organic framework photocatalysts for aminoalkyl radical-mediated halogen-atom transfer

Published:2023 Issue:5 Volume:11 Page:2472-2481
ISSN:2050-7488
Container-title:Journal of Materials Chemistry A
language:en
Short-container-title:J. Mater. Chem. A

Author:

Liu Xin¹,Guo Zhifen¹,Che Yan¹,Liu Xingbing¹,Yu Min¹,Lv Jiahuan¹,Li Mengying¹,Xing Hongzhu¹^ORCID,Chen Peng²

Affiliation:

1. Laboratory of Advanced Energy Materials, College of Chemistry, Northeast Normal University, Changchun 130021, China

2. Key Laboratory of Functional Inorganic Material Chemistry (MOE), School of Chemistry and Materials Science, Heilongjiang University, Harbin 150080, China

Abstract

Efficient photooxidation of amines by visible-light-responsive metal–organic frameworks generating α-aminoalkyl radicals to achieve halogen-atom transfer (XAT) reactions of dehalogenation, hydroalkylation and polyfluoroarylation.

Funder

Fundamental Research Funds for the Central Universities

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/TA/D2TA09819A

Reference74 articles.

1. Multifunctional Metal-Organic Frameworks for Photocatalysis

2. Visible Light Induced Organic Transformations Using Metal-Organic-Frameworks (MOFs)

3. Recent strategies to improve the photoactivity of metal–organic frameworks