Influence of the ligand frameworks on the coordination environment and properties of new phenylmercury(ii) β-oxodithioester complexes-Reference-Cited by-同舟云学术

Influence of the ligand frameworks on the coordination environment and properties of new phenylmercury(ii) β-oxodithioester complexes

Published:2015 Issue:12 Volume:44 Page:5909-5916
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Rajput Gunjan¹²³⁴⁵,Yadav Manoj Kumar¹²³⁴⁵,Drew Michael G. B.¹⁶⁷⁸,Singh Nanhai¹²³⁴⁵

Affiliation:

1. Department of Chemistry

2. Faculty of Science

3. Banaras Hindu University

4. Varanasi 221005

5. India

6. University of Reading

7. Reading

8. UK

Abstract

New luminescent PhHg(ii) dithioester complexes1–3have been synthesized and their crystal structures revealed O,S-coordination in1and2whereas less preferred S,S-coordination is observed in3. The keto-form of β-oxodithioester ligands is stabilized in these complexes.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/DT/C4DT03816A

Reference66 articles.

1. Transition Metal Dithiocarbamates: 1978-2003

2. Ring-Closing Metathesis and Nanoparticle Formation Based on Diallyldithiocarbamate Complexes of Gold(I): Synthetic, Structural, and Computational Studies

3. Exploiting the dithiocarbamate ligand in metal-directed self-assembly

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