Supramolecular assembly of pyrene-tetrathiafulvalene hybrids on graphene: structure–property relationships and biosensing activity

Author:

Garrido Marina1ORCID,Martínez-Periñán Emiliano2ORCID,Calbo Joaquín3ORCID,Rodríguez-Pérez Laura1ORCID,Aragó Juan3ORCID,Lorenzo Encarnación24ORCID,Ortí Enrique3ORCID,Martín Nazario14ORCID,Herranz Ma Ángeles1ORCID

Affiliation:

1. Departamento de Química Orgánica, Facultad de Ciencias Químicas, Universidad Complutense de Madrid, Avda. Complutense s/n, 28040 Madrid, Spain

2. Departamento de Química Analítica y Análisis Instrumental, Facultad de Ciencias, Universidad Autónoma de Madrid, C/Francisco Tomás y Valiente 7, 28049 Madrid, Spain

3. Instituto de Ciencia Molecular, Universidad de Valencia, 46980 Paterna, Spain

4. IMDEA-Nanociencia, c/Faraday 9, Campus Cantoblanco, 28049 Madrid, Spain

Abstract

The supramolecular functionalization of graphene with monopodal and tripodal pyrene receptors bearing a π-extended tetrathiafulvalene is investigated, and used to develop graphene-based electrodes for enzyme-based hydrogen peroxide sensing.

Funder

Ministerio de Ciencia e Innovación

Comunidad de Madrid

Generalitat Valenciana

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry

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