Electronic metal–support interactions enhance the ammonia synthesis activity over ruthenium supported on Zr-modified CeO2 catalysts-Reference-Cited by-同舟云学术

Electronic metal–support interactions enhance the ammonia synthesis activity over ruthenium supported on Zr-modified CeO2 catalysts

Published:2016 Issue:56 Volume:6 Page:51106-51110
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Ma Zhanwei¹²³⁴⁵,Xiong Xumao¹²³⁴⁵,Song Chengli¹²³⁴⁵,Hu Bin¹²³⁴⁵,Zhang Weiqiang⁶⁷⁵

Affiliation:

1. State Key Laboratory for Oxo Synthesis and Selective Oxidation

2. Lanzhou Institute of Chemical Physics

3. Chinese Academy of Sciences

4. Lanzhou 730000

5. China

6. Changchun Zhongke Haorong New Material Research Co., Ltd.

7. Changchun 130000

Abstract

Doping Zr⁴⁺ alters the electronic properties of the support. The electronic metal–support interaction produces the upshift of d-band center of Ru nanoparticles, which further influences the catalytic activity of ammonia synthesis.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/RA/C6RA10540H

Reference40 articles.

1. Study of potassium promoter effect for Ru/AC catalysts for ammonia synthesis

2. Promoter action of alkali nitrate in Raney ruthenium catalyst for activation of dinitrogen

3. Activation of nitrogen by alkali metal promoted transition metal I. Ammonia synthesis over ruthenium promoted by alkali metal

4. Ammonia synthesis using a stable electride as an electron donor and reversible hydrogen store

5. A vibrational spectroscopy study on the interaction of N2 with clean and K-promoted Fe(111) surfaces: π-bonded dinitrogen as precursor for dissociation

Cited by 32 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Bioinspired Catalysis with Biomimetic Clusters;Bioderived Materials: Harnessing Nature for Advanced Biochemical Handiwork;2024-02-29

2. Challenges and opportunities for the photo-(thermal) synthesis of ammonia;Green Chemistry;2024

3. Regulating oxygen vacancies by Zn atom doping to anchor and disperse promoter Ba on MgO support to improve Ru-based catalysts activity for ammonia synthesis;RSC Advances;2024

4. Hydrogen production by the catalytic decomposition of ammonia over a Ru/SiCeOx catalyst: The synergistic effect of Si addition;Fuel;2023-12

5. Lanthanide Oxides in Ammonia Synthesis Catalysts: A Comprehensive Review;Catalysts;2023-11-23