Selective cyclohexene oxidation to allylic compounds over a Cu-triazole framework via homolytic activation of hydrogen peroxide-Reference-Cited by-同舟云学术

Selective cyclohexene oxidation to allylic compounds over a Cu-triazole framework via homolytic activation of hydrogen peroxide

Published:2021 Issue:23 Volume:50 Page:7917-7921
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Ponchai Panyapat¹²³⁴^ORCID,Adpakpang Kanyaporn¹²³⁴^ORCID,Bureekaew Sareeya¹²³⁴⁵^ORCID

Affiliation:

1. School of Energy Science and Engineering

2. Vidyasirimedhi Institute of Science and Technology

3. Wangchan

4. Thailand

5. Research Network of NANOTEC-VISTEC on Nanotechnology for Energy

Abstract

Highly robust Cu-triazole MOF with abundant open-metal sites owning Lewis acid attributes is demonstrated to be an efficient catalyst for homolytic activation of H₂O₂ responsible for allylic compounds with 87% selectivity from cyclohexene oxidation.

Funder

National Science and Technology Development Agency

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/DT/D1DT00227A

Reference48 articles.

1. Oxidation mechanism of molecular oxygen over cyclohexene catalyzed by a cobalt l-glutamic acid complex

2. Highly selective oxidation of cyclohexene to 2-cyclohexene-1-one over polyoxometalate/metal–organic framework hybrids with greatly improved performances

3. Effective solvent-free oxidation of cyclohexene to allylic products with oxygen by mesoporous etched halloysite nanotube supported Co2+