Tunneling chemical exchange reaction D + HD → D2 + H in solid HD and D2 at temperatures below 1 K-Reference-Cited by-同舟云学术

Tunneling chemical exchange reaction D + HD → D2 + H in solid HD and D2 at temperatures below 1 K

Published:2016 Issue:42 Volume:18 Page:29600-29606
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Sheludiakov S.¹²³⁴⁵,Ahokas J.¹²³⁴⁵^ORCID,Järvinen J.¹²³⁴⁵,Zvezdov D.¹²³⁴⁵,Lehtonen L.¹²³⁴⁵,Vainio O.¹²³⁴⁵^ORCID,Vasiliev S.¹²³⁴⁵,Lee D. M.⁶²⁷⁸,Khmelenko V. V.⁶²⁷⁸^ORCID

Affiliation:

1. Wihuri Physical Laboratory

2. Department of Physics and Astronomy

3. University of Turku

4. 20014 Turku

5. Finland

6. Institute for Quantum Science and Engineering

7. Texas A&M University

8. USA

Abstract

The rates of the isotopic exchange reaction D + HD → D₂ + H were measured in solid HD and D₂:0.23%HD in a temperature range of 0.13–1.5 K.

Funder

Suomen Akatemia

Division of Materials Research

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2016/CP/C6CP05486B

Reference36 articles.

1. Experimental determination of the mechanism of the tunneling diffusion of H atoms in solid hydrogen: Physical exchange versus chemical reaction

2. H+H2Thermal Reaction: A Convergence of Theory and Experiment

3. Is the simplest chemical reaction really so simple?

4. Quantum dynamics of tunneling dominated reactions at low temperatures

5. Geometric Phase Appears in the Ultracold Hydrogen Exchange Reaction

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