Augmented polyhydrazone formation in water by template-assisted polymerization using dual-purpose supramolecular templates

Author:

Zheng Kai12345,He Chang12345,Nour Hany F.12345,Zhang Zhao12345,Yuan Tianyu12345ORCID,Traboulsi Hassan6789,Mazher Javed6789,Trabolsi Ali10111213ORCID,Fang Lei14151617ORCID,Olson Mark A.12345ORCID

Affiliation:

1. Institute for Molecular Design and Synthesis

2. School of Pharmaceutical Science and Technology

3. Tianjin University

4. Tianjin

5. P.R. China

6. Chemistry Department and Physics Department

7. King Faisal University

8. Al Ahsa 31982

9. Kingdom of Saudi Arabia

10. Chemistry Program

11. New York University Abu Dhabi (NYUAD)

12. Experimental Research Building (C1)

13. United Arab Emirates

14. Department of Chemistry and Department of Materials Science and Engineering Department

15. Texas A&M University

16. College Station

17. USA

Abstract

Template-assisted polymerization using donor–acceptor supramolecular templates results in higher Mw and Mn values, decreased critical hydrogelation concentrations, and increased gel recovery velocity following shear-induced breakdown.

Funder

National Basic Research Program of China

Welch Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Polymers and Plastics,Biochemistry,Bioengineering

Reference121 articles.

1. Molecular organization, portal to supramolecular chemistryStructural analysis of the factors associated with molecular organization in coordination and inclusion chemistry, including the coordination template effect

2. Expanding roles for templates in synthesis

3. S. Anderson and H. L.Anderson , Templated Organic Synthesis , ed. F. Diederich and P. J. Stang , Wiley-VCH , Weinheim , 1999

4. Chemical synthesis gets a fillip from molecular recognition and self-assembly processes

5. Templates in Chemistry II , ed. C. A. Schalley , F. Vogtle and K. H. Dotz , Springer , Berlin , 2005

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