Are multiple oxygen species selective in ethylene epoxidation on silver?-Reference-Cited by-同舟云学术

Are multiple oxygen species selective in ethylene epoxidation on silver?

Published:2018 Issue:4 Volume:9 Page:990-998
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Carbonio Emilia A.¹²³⁴⁵^ORCID,Rocha Tulio C. R.⁶⁷⁸⁹^ORCID,Klyushin Alexander Yu.¹²³⁴⁵^ORCID,Píš Igor¹⁰¹¹¹²¹³¹⁴^ORCID,Magnano Elena¹⁰¹¹¹²¹³¹⁵,Nappini Silvia¹⁰¹¹¹²¹³^ORCID,Piccinin Simone¹⁶¹⁷¹⁸¹³^ORCID,Knop-Gericke Axel⁴⁵¹⁹³,Schlögl Robert⁴⁵¹⁹³²⁰,Jones Travis E.⁴⁵¹⁹³^ORCID

Affiliation:

1. Helmholtz-Zentrum Berlin für Materialien und Energie GmbH

2. 12489 Berlin

3. Germany

4. Department of Inorganic Chemistry

5. Fritz-Haber-Institut der Max-Planck-Gesellschaft

6. Brazilian Synchrotron Light Laboratory (LNLS)

7. Brazilian Center for Research on Energy and Materials (CNPEM)

8. Campinas

9. Brazil

10. IOM-CNR

11. Laboratorio TASC

12. Trieste

13. Italy

14. Elettra-Sincrotrone Trieste S.C.p.A.

15. Department of Physics

16. CNR-IOM DEMOCRITOS

17. Consiglio Nazionale delle Ricerche—Istituto Officina dei Materiali

18. 34136 Trieste

19. 14195 Berlin

20. Department of Heterogeneous Reactions

Abstract

We show atomic oxygen on an unreconstructed Ag(110) surface has a O 1s binding energy ≤ 528 eV and its stable at low coverages. Our findings point to the idea of multiple selective oxygen species in ethylene epoxidation on Ag.

Funder

Alexander von Humboldt Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2018/SC/C7SC04728B

Reference79 articles.

1. The mechanism of ethylene epoxidation

2. Surface science and the silver-catalyzed epoxidation of ethylene: an industrial perspective

3. Chapter 9. Ethylene Epoxidation over Silver Catalysts

4. Combined in situ XPS and PTRMS study of ethylene epoxidation over silver

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