Polypyrrole-functionalized ruthenium carbene catalysts as efficient heterogeneous systems for olefin epoxidation

Author:

Dakkach Mohamed12345,Fontrodona Xavier123,Parella Teodor67,Atlamsani Ahmed4589,Romero Isabel123,Rodríguez Montserrat123

Affiliation:

1. Departament de Química i Serveis Tècnics de Recerca

2. Universitat de Girona

3. E-17071 Girona, Spain

4. Laboratoire des Matériaux et Systèmes Interfaciaux

5. Département de Chimie

6. Departament de Química i Servei de RMN Universitat Autònoma de Barcelona

7. E-08193 Barcelona, Spain

8. Faculté des Sciences

9. 93000 Tétouan, Morocco

Abstract

New Ru-pyrrole complexes are described among which a Ru-OH2complex that has been anchored onto graphite supports and tested in olefin epoxidation, displaying up to several thousand TON values.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Reference59 articles.

1. Z. Ma and F.Zaera , in Heterogeneous Catalysis by Metals. Encyclopedia of Inorganic and Bioinorganic Chemistry , John Wiley & Sons , 2011

2. C. N. Satterfield , in Heterogeneous Catalysis in Industrial Practice , Krieger Publishing , Malabar , 1996

3. Heterogenization of homogeneous catalytic systems

4. Recent Progress in the Heterogenization of Complexes for Single‐Site Epoxidation Catalysis

5. Chiral Salen Complexes:  An Overview to Recoverable and Reusable Homogeneous and Heterogeneous Catalysts

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