Chemo-selective Stille-type coupling of acyl-chlorides upon phosphine-borane Au(<scp>i</scp>) catalysis-Reference-Cited by-同舟云学术

Chemo-selective Stille-type coupling of acyl-chlorides upon phosphine-borane Au(i) catalysis

Published:2024 Issue:14 Volume:15 Page:5187-5191
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Hidalgo Nereida¹²^ORCID,Le Gac Arnaud¹,Mallet-Ladeira Sonia³,Bouhadir Ghenwa¹^ORCID,Bourissou Didier¹^ORCID

Affiliation:

1. CNRS/Université Paul Sabatier, Laboratoire Hétérochimie Fondamentale et Appliquée (LHFA UMR 5069), 118 Route de Narbonne, 31062 Toulouse Cedex 09, France

2. Departamento de Química Inorgánica, Universidad de Sevilla, 41071 Sevilla, Spain

3. Institut de Chimie de Toulouse (FR 2599), 118 Route de Narbonne, 31062 Toulouse Cedex 09, France

Abstract

Phosphine-boranes do not promote oxidative addition of acyl chlorides to gold, but the phosphine-borane gold triflimide complex [iPr2P(o-C6H4)BCy2]AuNTf2 was found to catalyze the coupling of acyl chlorides and aryl stannanes.

Funder

Université Toulouse III - Paul Sabatier

Centre National de la Recherche Scientifique

Région Occitanie Pyrénées-Méditerranée

Agence Nationale de la Recherche

Universidad de Sevilla

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/SC/D3SC06193K

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