Preparation of a bispyridine based porous organic polymer as a new platform for Cu(ii) catalyst and its use in heterogeneous olefin epoxidation
Author:
Affiliation:
1. Department of Chemistry
2. Research Institute for Natural Sciences
3. Korea University
4. Seoul 136-701
5. Republic of Korea
6. Department of Fine Chemistry
7. Seoul National University of Science and Technology
8. Seoul 136-743
Abstract
A new type of bispyridine (bpy) incorporated POP was prepared via a cobalt-catalyzed acetylene trimerization. Subsequent metalation of CuCl2 gave POP-Cu(ii) which displayed outstanding olefin oxidation activity.
Funder
National Research Foundation of Korea
Korea University
Publisher
Royal Society of Chemistry (RSC)
Subject
Materials Chemistry,General Chemistry,Catalysis
Link
http://pubs.rsc.org/en/content/articlepdf/2018/NJ/C8NJ02214C
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3. Cu(ii)Cl2 containing bispyridine-based porous organic polymer support prepared via alkyne–azide cycloaddition as a heterogeneous catalyst for oxidation of various olefins;New Journal of Chemistry;2020
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