Preparation of a bispyridine based porous organic polymer as a new platform for Cu(ii) catalyst and its use in heterogeneous olefin epoxidation

Author:

Yi Jigyoung12345,Ahn Hye Mi6785,Yoon Jong Ho12345,Kim Cheal6785ORCID,Lee Suk Joong12345ORCID

Affiliation:

1. Department of Chemistry

2. Research Institute for Natural Sciences

3. Korea University

4. Seoul 136-701

5. Republic of Korea

6. Department of Fine Chemistry

7. Seoul National University of Science and Technology

8. Seoul 136-743

Abstract

A new type of bispyridine (bpy) incorporated POP was prepared via a cobalt-catalyzed acetylene trimerization. Subsequent metalation of CuCl2 gave POP-Cu(ii) which displayed outstanding olefin oxidation activity.

Funder

National Research Foundation of Korea

Korea University

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

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