Synthesis, structure and NMR studies of trinuclear Mo3S4 clusters coordinated with dithiophosphate and chiral carboxylate ligands

Author:

Gushchin Artem L.12345,Hernandez-Molina Rita678910,Anyushin Alexander V.1234,Gallyamov Marsel R.1234,Gonzalez-Platas Javier11128910,Moroz Nikolay K.1234,Sokolov Maxim N.12345

Affiliation:

1. Nikolaev Institute of Inorganic Chemistry

2. Siberian Branch of the Russian Academy of Sciences

3. 630090 Novosibirsk

4. Russia

5. Novosibirsk State University

6. Departamento de Química Inorgánica

7. Facultad de Química

8. Universidad de La Laguna

9. Tenerife

10. Spain

11. Departamento de Física

12. Servicio Integrado de Difracción de Rayos X

Abstract

Introducing chirality into the Mo3S4 cluster has been achieved through coordination of (S)-mandelate and (S)-phenyllactate ligands affording new complexes as a pair of diastereoisomers, (PS) and (MS), represented in the scheme.

Funder

Russian Foundation for Basic Research

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

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