Highly electron-poor Buchwald-type ligand: application for Pd-catalysed direct arylation of thiophene derivatives and theoretical consideration of the secondary Pd0–arene interaction-Reference-Cited by-同舟云学术

Highly electron-poor Buchwald-type ligand: application for Pd-catalysed direct arylation of thiophene derivatives and theoretical consideration of the secondary Pd0–arene interaction

Published:2015 Issue:45 Volume:44 Page:19642-19650
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Korenaga Toshinobu¹²³⁴⁵,Sasaki Ryo¹²³⁴⁵,Shimada Kazuaki¹²³⁴⁵

Affiliation:

1. Department of Chemistry and Bioengineering

2. Faculty of Engineering

3. Iwate University

4. Morioka

5. Japan

Abstract

Highly electron-poor SPhos ligands stabilised the Pd complex by secondary Pd⁰–arene interaction.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/DT/C5DT01991E

Reference67 articles.

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2. Fluoroarylphosphines as ligands

3. Electron-Poor Chiral Diphosphine Ligands: High Performance for Rh-Catalyzed Asymmetric 1,4-Addition of Arylboronic Acids at Room Temperature

4. Ligand Electronic Effect on Reductive Elimination of Biphenyl from cis-[Pt(Ph)2(diphosphine)] Complexes Bearing Electron-Poor Diphosphine: Correlation Study between Experimental and Theoretical Results

5. Synthesis and Application of 2,6-Bis(trifluoromethyl)-4-pyridyl Phosphanes: The Most Electron-Poor Aryl Phosphanes with Moderate Bulkiness

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