Stoichiometric and catalytic C–F bond activation by the trans-dihydride NHC complex [Ru(IEt2Me2)2(PPh3)2H2] (IEt2Me2= 1,3-diethyl-4,5-dimethylimidazol-2-ylidene)-Reference-Cited by-同舟云学术

Stoichiometric and catalytic C–F bond activation by the trans-dihydride NHC complex [Ru(IEt2Me2)2(PPh3)2H2] (IEt2Me2= 1,3-diethyl-4,5-dimethylimidazol-2-ylidene)

Published:2015 Issue:45 Volume:44 Page:19597-19605
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Cybulski Mateusz K.¹²³⁴,Riddlestone Ian M.¹²³⁴,Mahon Mary F.¹²³⁴,Woodman Timothy J.⁵²³⁴,Whittlesey Michael K.¹²³⁴

Affiliation:

1. Department of Chemistry

2. University of Bath

3. Bath BA2 7AY

4. UK

5. Department of Pharmacy and Pharmacology

Abstract

Multiple catalytic hydrodefluorination steps take place with thetrans-dihydride complex [Ru(IEt₂Me₂)₂(PPh₃)₂H₂] (1), taking C₆F₆to tri-, di- and mono-fluorobenzenes.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/DT/C5DT01996F

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