Derivatization of an especially electron-rich diborane-Reference-Cited by-同舟云学术

Derivatization of an especially electron-rich diborane

Published:2022 Issue:5 Volume:58 Page:693-696
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Vogler Daniel¹,Haas Lea¹,Wolf Nina¹,Kaifer Elisabeth¹,Himmel Hans-Jörg¹^ORCID

Affiliation:

1. Inorganic Chemistry, Ruprecht-Karls-University Heidelberg Im Neuenheimer Feld 270, Heidelberg 69120, Germany

Abstract

Novel symmetric and unsymmetric diboranes with sp3-hybridized boron atoms and especially electron-donating bridging guanidinate substituents are synthesized and their properties analysed. Moreover, dismutation equilibria are disclosed.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2022/CC/D1CC06359F

Reference16 articles.

1. Substitution Reactions at Tetracoordinate Boron: Synthesis of N-Heterocyclic Carbene Boranes with Boron−Heteroatom Bonds

2. Diboron(4) Compounds: From Structural Curiosity to Synthetic Workhorse

3. Formation and Reactivity of Electron-Precise B−B Single and Multiple Bonds

4. Recent advances in transition metal diborane(6), diborane(4) and diborene(2) chemistry

5. Nucleophilic Neutral Diborane(4) Compounds with sp 3 –sp 3 ‐Hybridized Boron Atoms

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