Post-synthetic modification of a macrocyclic receptor via regioselective imidazolium ring-opening-Reference-Cited by-同舟云学术

Post-synthetic modification of a macrocyclic receptor via regioselective imidazolium ring-opening

Published:2016 Issue:7 Volume:7 Page:4148-4157
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Shang Jia¹²³⁴,Rambo Brett M.⁵⁶⁷⁸,Hao Xiang⁹¹⁰¹¹⁴,Xiang Jun-Feng⁹¹⁰¹¹⁴,Gong Han-Yuan¹²³⁴,Sessler Jonathan L.⁵⁶⁷⁸⁵

Affiliation:

1. College of Chemistry

2. Beijing Normal University

3. Beijing 100875

4. P. R. China

5. Department of Chemistry

6. The University of Texas at Austin

7. Austin

8. USA

9. Institute of Chemistry

10. Chinese Academy of Sciences

11. Beijing 100190

Abstract

Shown in graphic form is the use of mild basic conditions to effect the post-synthetic, ring-opening based modification of a tetraimidazolium macrocycle known as the “Texas box”. This ring opening modulates the intrinsic binding characteristics of the system.

Funder

Welch Foundation

National Natural Science Foundation of China

Beijing Municipal Commission of Education

Beijing Normal University

National Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/SC/C5SC04860E