Affiliation:
1. State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, P.R. China
Abstract
A Pd–COOCH3 species in the vapor-phase carbonylation of methyl nitrite is revealed to have two-fold reactivity, where the nucleophilicity of the Pd–C bond enables C–C coupling to give DMO and the electrophilicity of the π* orbital facilitates C–O coupling to afford DMC.
Funder
Natural Science Foundation of Fujian Province
National Natural Science Foundation of China
National Key Research and Development Program of China
Chinese Academy of Sciences
Yulin University
Dalian National Laboratory for Clean Energy
Publisher
Royal Society of Chemistry (RSC)
Cited by
2 articles.
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