Effect of Mn2+ substitution on the structure, properties and HER activity of cadmium phosphochlorides
Author:
Affiliation:
1. New Chemistry Unit
2. Sheikh Saqr Laboratory
3. School of Advance Materials
4. Theoretical Science Unit
5. Jawaharlal Nehru Centre for Advanced Scientific Research
Abstract
Mn2+ prefers the Cd-sites having larger number of tightly bounded Cl-ligands. Pure Cd7P4Cl6 exhibits n-type conductivity whereas Cd5.8Mn1.2P4Cl6 exhibits p-type conductivity. The HER activity of Cd7−yMnyP4Cl6 is superior to that of pristine Cd7P4Cl6.
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemical Engineering,General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2020/RA/C9RA10711H
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