Theoretical investigations toward the [3 + 2]-dipolar cycloadditions of nitrones with vinyldiazoacetates catalyzed by Rh2(R-TPCP)4: mechanism and enantioselectivity-Reference-Cited by-同舟云学术

Theoretical investigations toward the [3 + 2]-dipolar cycloadditions of nitrones with vinyldiazoacetates catalyzed by Rh2(R-TPCP)4: mechanism and enantioselectivity

Published:2016 Issue:59 Volume:6 Page:53839-53851
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Ma Ling-Ling¹²³⁴⁵,Wang Wan¹²³⁴⁵,Wang Gui-Chang¹²³⁴⁵

Affiliation:

1. Department of Chemistry

2. Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education)

3. Nankai University

4. Tianjin 300071

5. P. R. China

Abstract

The mechanism of Rh₂(R-TPCP)₄-catalyzed [3 + 2]-dipolar cycloadditions between vinyldiazoacetate and nitrone to form 2,5-dihydroisoxazole has been studied by ONIOM methodology calculations including density functional theory and PM6 theory.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/RA/C6RA07873G

Reference90 articles.

1. Organocatalytic and Stereoselective [3 + 2] Cycloadditions of Azomethine Imines with α,β-Unsaturated Aldehydes

2. Enantioselective 1,3-Dipolar Cycloaddition of Cyclic Enones Catalyzed by Multifunctional Primary Amines: Beneficial Effects of Hydrogen Bonding

3. Highly Enantioselective and Diastereoselective 1,3-Dipolar Cycloaddition Reactions between Azomethine Imines and 3-Acryloyl-2-oxazolidinone Catalyzed by Binaphthyldiimine−Ni(II) Complexes