Affiliation:
1. Jiangsu Key Laboratory of Advanced Catalytic Materials & Technology, School of Petrochemical Engineering, Changzhou University, Changzhou 213164, China
Abstract
We report herein an iridium-catalyzed asymmetric allylic esterification of racemic secondary allylic alcohols with carboxylic acids under mild conditions with broad functional group tolerance, exhibiting excellent regio- (b/l > 19 : 1) and enantioselectivity (up to >99% ee).
Funder
National Natural Science Foundation of China
Jiangsu Key Laboratory of Advanced Catalytic Materials and Technology Department
Changzhou University
Publisher
Royal Society of Chemistry (RSC)
Subject
Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis
Reference38 articles.
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5. B. M.Trost and C.Lee , in Catalytic Asymmetric Synthesis , ed. I.Ojima , Wiley-VCH , New York , 2nd edn, 2010 , p. 593
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