Superlinear amplification of the first hyperpolarizability of linear aggregates of DANS molecules

Author:

Sanyal Somananda12345ORCID,Sissa Cristina12345ORCID,Terenziani Francesca12345ORCID,Pati Swapan K.6789ORCID,Painelli Anna12345ORCID

Affiliation:

1. Department of Chemistry

2. Life Science and Environmental Sustainability

3. Parma University

4. 43124 Parma

5. Italy

6. New Chemistry Unit and Theoretical Sciences Unit

7. Jawaharlal Nehru Centre for Advanced Scientific Research

8. Bangalore-64

9. India

Abstract

A comprehensive study of optical properties of DANS in different environments explains the observed ∼30-fold enhancement of the hyper-Rayleigh signal of DANS@CNT vs. DANS in solution in terms of collective and cooperative phenomena occurring in aggregates of less than 10 aligned molecules.

Funder

FP7 People: Marie-Curie Actions

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

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