Dynamically activating Ni-based catalysts with self-anchored mononuclear Fe for efficient water oxidation

Author:

Zhang Zhiyuan1,Luo Yuting12,Wang Kun1,Yu Qiangmin1,Kang Xin1,Liu Yingqi1,Xie Ke2,Lv Zhengxing3,Liu Zhibo4,Yang Fengning1,Liu Heming1,Liu Ke3,Li Jiong3ORCID,Zhou Guangmin1ORCID,Ren Wencai4ORCID,Cheng Hui-Ming145,Li Jia1,Zhang Shuo3ORCID,Liu Bilu1ORCID

Affiliation:

1. Shenzhen Geim Graphene Center, Tsinghua-Berkeley Shenzhen Institute & Institute of Materials Research, Shenzhen International Graduate School, Tsinghua University, Shenzhen 518055, P. R. China

2. Department of Electrical and Computer Engineering, University of Toronto, 35 St George Street, Toronto, Ontario M5S 1A4, Canada

3. Shanghai Synchrotron Radiation Facility, Shanghai Advanced Research Institute, Chinese Academy of Sciences, Shanghai 201210, China

4. Shenyang National Laboratory for Materials Sciences, Institute of Metal Research, Chinese Academy of Sciences, Shenyang, Liaoning 110016, P. R. China

5. Shenzhen Institute of Advanced Technology, Chinese Academy of Sciences, Shenzhen 518055, China

Abstract

A surface engineering strategy to form a highly active Fe–Ni structure on the surfaces of Ni-based catalysts. The surface Fe is readily oxidized under OER conditions, compensating for the charges of Ni and increasing the activity of Ni active sites.

Funder

National Natural Science Foundation of China

National Science Fund for Distinguished Young Scholars

Basic and Applied Basic Research Foundation of Guangdong Province

Guangdong Province Introduction of Innovative R&D Team

Shenzhen Fundamental Research Program

Guangdong Provincial Pearl River Talents Program

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

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