PBLG as a versatile liquid crystalline medium for anisotropic NMR data acquisition

Author:

Ndukwe Ikenna E.1234ORCID,Wang Xiao1234ORCID,Pelczer István5674ORCID,Reibarkh Mikhail1234ORCID,Williamson R. Thomas1234ORCID,Liu Yizhou1234ORCID,Martin Gary E.1234ORCID

Affiliation:

1. Analytical Research and Development (Rahway)

2. Merck & Co. Inc

3. Kenilworth

4. USA

5. Princeton University

6. Department of Chemistry

7. Princeton

Abstract

The chiral nematic phase of poly-γ-benzyl-l-glutamate (PBLG) formed in a chloroform–DMSO co-solvent system can be used as a versatile alignment medium for the acquisition of high quality anisotropic NMR data for molecules of varying polarities.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Reference44 articles.

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3. Residual Dipolar Couplings in Structure Determination of Natural Products

4. Application of anisotropic NMR parameters to the confirmation of molecular structure

5. Computer‐Assisted 3D Structure Elucidation of Natural Products using Residual Dipolar Couplings

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